Caffeine not only acts as a natural pesticide, but also as a natural herbicide
Toxicity Based on LD50 Values
• Nicotine LD50 50-60
• Gasoline LD50 50-100
• Caffeine LD50 192
• 2,4-D LD50 699
• Aspirin LD50 750
• Malathion LD50 1000-2800
• Salt LD50 3320-4180
• Roundup LD50 4300
• Tordon LD50 8200
http://www.colostate.edu/dept/sjbrc/owm/Organic%20herbicides%20HO.pdf