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Airports are the most interesting place to people watch. Also, look around. Wander the terminals. The last time I flew, I was walking around an empty terminal just talking on the phone. I happened to see an odd white thing sitting on the windowsill. It turns out it was an iPhone. Turned it on, had almost full battery. Went through the text messages and recent calls (no ICE), made a few calls, and found the owner's husband. Apparently she was aware she left it, called the airline which conducted a "thorough search" and failed. Lol, they didn't search at all. Got an address and mailed it back. Was just happy to help out, but a month or so later a $25 VISA gift card showed up sent to my return address. Very nice. :) Also played around on YouTube the entire time I was waiting for the flight on her iPhone lol.
Another time I was coming home from a climbing trip and had way too much stuff to make the checked baggage weight. I ended up taking my climbing rope and just putting it on my back, over my already stuffed backpack. That started a bunch of interesting conversations, including being asked if I was going to rappel out of the plane. Got talking about one guy's experiences climbing in Alaska back in the day.
Coming back from Africa I overheard some kids talking about skiing. Approached them with the line "You're the first Americans I have seen in over a month" and proceeded to have a great time talking about skiing, college, Africa, etc.
Lots more, but those come to mind right now.