I'd give you two pieces of advice:
1. Look for the seasonnaire based resorts. I.e. don't head to Val D'Isere or the Trois Vallées as they are set up for tourists. Resorts like Morzine/Avoriaz Tignes, Mayrhofen and Laax are geared towards seasonnaires because of their emphasis on freestyle/freeride.
2.On the jobs front, look for the right kind of job. The chalet hosts/hotel hosts in my opinion worked too hard and tended to save themselves for the evening. I worked as a kitchen porter and I found that as we were doing the shittiest job going, all we cared about was the skiing. Also, ski rental shops are a good bet, as even though they work in the day, they get reasonable time off and , often take advantage of the powder days.
As for the people, If you look hard enough you'll find plenty of guys looking to ride all the time, if not in your company, then in the resort.