Yeah I've done it before. Make sure you use a sturdy tripod, that there are absolutely no clouds in the sky, and that their is a new moon. Also, get away from cities or town, as light pollution looks really ugly in long exposures. Finally, keep the aperture open pretty wide and expose for 30 minutes max if your shooting with a dslr, because shit starts to get noisy/grainy. If shooting film, go for as long as you want but remember to keep track of reciprocity failure (search google for all this). Here's one I shot last summer. It was around a 30 minute exposure: