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Yeah man, 3M scotchguard is great. A lot of materials lose their integrity of water repellency after a season or so. It helps to tighten them up a little bit. Also, you can spray it on a sweatshirt for the spring and it helps a lot...Good stuff.
Ive never had it mess up colors, depending on the brand of waterproofing sometimes i can smell really raunchy and the smell will stick for a while. Other than that the stuff works great in general.
It depends what your putting it on, what its original waterproofing is, the material, and the quality of the spray/gel. If its leather there is actual leather waterproofing that helps with that. Most of the stuff i have used has stiffened the fabric a little initialy, other than that and smell thats all i have noticed. And the obvious increased waterproofing.
basically, most jackets have a water repellant dwr (durable water repellant) coating. the spray on and wash-in dwr coatings simply revive and repair the original coating as it begins to wear off. scotchguard works fine, but i prefer sprays that are more specifically designed for outerwear such as tectron and revivex. the nikwax wash-in stuff works fine too.